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I need to change certificate some times along the application execution. I destroy TChromiun but it's inssuficient, the event "OnSelectClientCertificate" is fired one time only. It's necesary reset the application.
I can't test certificates right now but I guess it should ask for a new certificate if you logout from that website.
If that isn't enough then try to destroy that browser following the "destruction steps" given in the code comments of every demo and then create a new browser with a new request context as shown in the MDIBrowser demo.
Browsers created with different request contexts are completely independent and they should ask for a new certificate.