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Actually the Chrome proxy settings, it's just a shortcut for the Windows 11 proxy settings ; i could not see any internal proxy settings , looks likes Chrome just use the Windows settings ; if i configure this same proxy on Windows, it will work.
Then try the official CEF sample application and use the --proxy-server command line switch to configure the proxy :
https://cef-builds.spotifycdn.com/cef_binary_130.1.16%2Bg5a7e5ed%2Bchromium-130.0.6723.117_windows64_client.tar.bz2
Read this page to know all the details about that switch :
https://www.chromium.org/developers/design-documents/network-settings/